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Beilstein J. Org. Chem. 2019, 15, 2105–2112, doi:10.3762/bjoc.15.208
Graphical Abstract
Scheme 1: The representative synthesis of thioxanthylium salts.
Figure 1: The generality of diaryl sulfide 1 and benzoyl chloride 2. aThe reaction was carried out with 1a (2...
Figure 2: The UV–vis spectra of thioxanthylium salt (0.1 mM) in CH3CN.
Figure 3: Frontier orbitals of thioxanthylium salts, calculated by DFT at the B3LYP/6-31G(d,p) level of Orca....
Figure 4: UV–vis spectra of thioxanthylium salts 3b and 4b (0.1 mM) in CH3CN.
Figure 5: Structure of thioxanthylium salt 4.
Figure 6: Cyclic voltammograms of thioxanthylium salts 3b and 4b.